Towards High Efficiency and Low Roll‐Off Orange Electrophosphorescent Devices by Fine Tuning Singlet and Triplet Energies of Bipolar Hosts Based on Indolocarbazole/1, 3, 5‐Triazine Hybrids

Orange‐emitting phosphorescent organic light‐emitting diodes (PHOLEDs) are drawing more and more attention; however, high‐performance hosts designed for orange PHOLEDs are rare. Here, four indolocarbazole/1, 3, 5‐triazine hybrids are synthesized to optimize the singlet and triplet energies, as well as transporting properties, for ideal orange PHOLEDs. By introducing moieties with different electronegativity, a graded reduction of the singlet and triplet energies is achieved, resulting in minimum injection barrier and minimum energy loss. Besides, the charge transporting abilities are also tuned to be balanced on the basis of the bipolar features of those materials. The optimized orange PHOLED shows a maximum external quantum efficiency (EQE) of 24.5% and a power efficiency of 64 lm W^–1, both of which are among the best values for orange PHOLEDs. What is more, the efficiency roll‐off is extremely small, with an EQE of 24.4% at 1000 cd m^–2 and 23.8% at 10 000 cd m^–2, respectively, which is the lowest efficiency roll‐off for orange PHOLEDs to date, resulting in the highest EQE for orange PHOLEDs when the luminance is above 1000 cd m^–2. Besides the balanced charges, the small roll‐off is also attributed to the wide recombination zone resulting from the bipolar features of the hosts.     

Highly Improved Sb2S3 Sensitized‐Inorganic–Organic Heterojunction Solar Cells and Quantification of Traps by Deep‐Level Transient Spectroscopy

The light‐harvesting Sb₂S₃ surface on mesoporous‐TiO₂ in inorganic–organic heterojunction solar cells is sulfurized with thioacetamide (TA). The photovoltaic performances are compared before and after TA treatment, and the state of the Sb₂S₃ is investigated by X‐ray diffraction, X‐ray photoelectron spectroscopy, and deep‐level transient spectroscopy (DLTS). Although there are no differences in crystallinity and composition, the TA‐treated solar cells exhibit significantly enhanced performance compared to pristine Sb₂S₃‐sensitized solar cells. From DLTS analysis, the performance enhancement is mainly attributed to the extinction of trap sites, which are present at a density of (2–5) × 10¹⁴ cm^?3 in Sb₂S₃, by TA treatment. Through such a simple treatment, the cell records an overall power conversion efficiency (PCE) of 7.5% through a metal mask under simulated illumination (AM 1.5G, 100 mW cm^–2) with a very high open circuit voltage of 711.0 mV. This PCE is, thus far, the highest reported for fully solid‐state chalcogenide‐sensitized solar cells.     

Transmission Power Control for IEEE 802.15.6 Body Area Networks

Energy consumption is an important issue in body area networks (BANs). In this letter, we propose an energy efficient transmission power control scheme for IEEE 802.15.6 BANs, which can improve energy efficiency by adaptively adjusting the transmit power in an on‐demand way to adapt to varying channel environments. Simulations are performed to evaluate the performance, and it is shown that the proposed power control scheme outperforms traditional ones in terms of energy efficiency without significant reliability degradation.     

An adaptive power pricing scheme for improved fairness in energy‐constrained cooperative networks

This paper presents an adaptive power pricing scheme to address the fairness issue with relay selection and power allocation in decode‐and‐forward‐based opportunistic relaying networks, which is focused on the scenario where a distributed energy‐constrained cooperative communication system is employed over Rayleigh fading channels. Specifically, the proposed scheme is conducted analytically by obtaining the mathematical expression for the symbol error probability using the statistical characteristic of the signal‐to‐noise ratio, and it also takes the residual energy of nodes into consideration. Numerical results show that the proposed scheme has the advantage of better system reliability and further improves the throughput of the whole network compared with previous algorithms without considering fairness. Copyright © 2013 John Wiley & Sons, Ltd.     

Achieving above 30% external quantum efficiency for inverted phosphorescence organic light-emitting diodes based on ultrathin emitting layer

High efficiency inverted phosphorescence organic light-emitting diodes (PhOLEDs) based on ultrathin undoped and doped emitting layer (EML) have been developed. Compared to conventional device, the inverted PhOLED with 0.5 nm undoped EML exhibits significantly larger external quantum efficiency (EQE), due to effective energy transfer from the excited host to the emitter. According to the atomic force microscopy image of EML, the 0.5 nm emitter sandwiched by two hosts can be considered as the emitter doped in two hosts. The inverted device with intentionally doped ultrathin EML (1.5 nm) exhibits the maximum EQE of 31.1%, which is attributed to optimized charge balance and preferred horizontal orientation of emitter. However, such inverted device has large efficiency roll-off at high brightness because of triplet–triplet annihilation process within the ultrathin EML. This can be improved by broadening the doped EML. The inverted device with 10.5 nm doped EML has about EQE of 20 % at 10,000 cd/m². It is expected that our inverted PhOLED will promote development of high efficiency active-matrix organic light-emitting diodes based on the n-type Indium Gallium Zinc Oxide thin film transistor.     

GB 21520-201X显示器能效新标准解读与分析

针对GB21520-201X显示器能效新标准,结合与旧版能效标准比较所得的差异进行了相关的解读与分析。结果表明,新标准在适用范围、能源效率指标部分进行了更新,增加了高性能显示器、睡眠状态功率等概念。并通过实际的测试,对高性能显示器的标准符合性进行了分析。     

Energy efficiency comparison between distributed and co‐located MIMO systems

Energy efficiency (EE) is becoming more and more important in future wireless communications because of limited battery power in mobile terminals. In this paper, we compare EE of the distributed MIMO (D‐MIMO) and co‐located MIMO (C‐MIMO) in uplink systems. Taking into account both circuit and transmit power, we derive an analytical expression for EE of D‐MIMO and C‐MIMO systems in a composite Rayleigh‐lognormal channel. What is more, an optimization algorithm is proposed to get the optimal EE values while satisfying given spectral efficiency requirement for both D‐MIMO and C‐MIMO systems. Simulation results show that D‐MIMO systems are more energy effective than C‐MIMO systems when considering the realistic systems, and the optimal EE can be obtained by the proposed algorithm while satisfying given spectral efficiency requirement. Copyright © 2012 John Wiley & Sons, Ltd.     

Thermal buffer materials for enhancement of device performance of organic light emitting diodes fabricated by laser imaging process

Laser Induced Thermal Imaging (LITI) is a laser addressed thermal patterning technology with unique advantages such as an excellent uniformity of transfer film thickness, a capability of multilayer stack transfer and a possibility to fabricate high resolution as well as large-area display. Nevertheless, it has been an obstacle to use such a laser imaging process as a commercial technology so far because of serious deterioration of the device performances plausibly due to a re-orientation of the molecular stacking especially in the emitting layer during thermal transfer process. To improve device performances, we devised a new concept to suppress the thermal degradation during such kind of thermal imaging process by using a high molecular weight small molecular species with large steric hindrance as well as high thermostability as a thermal buffer layer to realize highly efficient LITI devices. As a result, we obtained very high relative efficiency (by EQE) up to 91.5% at 1000 cd/m² from the LITI devices when we utilize 10-(naphthalene-2-yl)-3-(phenanthren-9-yl)spiro[benzo[ij]tetraphene-7,9′-fluorene] as a thermal buffer material.     

TFT-LCD工厂能源消费结构及用能特点分析

TFT-LCD工厂具有投资高、建筑体量大、能源消耗量大的特点。为了在工厂设计、建设、运营阶段有的放矢地做好节能降耗工作,针对重点耗能工序、耗能设备以及影响能耗的关键因素,采取科学、合理、可行的节能措施和节能工程,从而达到更好的节能效果。本文对TFT-LCD工厂能源消耗种类、能源消费结构及能源分布特点、主要能源加工转换过程中的能量平衡、能效指标等进行了研究分析。总结我院多年来完成的同类项目经验数据,通过层次分析法、能量平衡分析方法、标准对照方法等对主要用能体系及用能特点进行深入剖析。分析结果表明,电力是TFT-LCD项目消耗量最大的能源,约占全厂综合能耗的75%以上,其中工艺生产设备电力消耗约占全厂用电的45%~50%,阵列为最主要的工艺耗能工序,厂务系统中冷水机组等动力设备是主要耗能设备;氮气是消耗量最大的耗能工质,约占全厂综合能耗的20%。能源消费结构及用能特点基本符合此类工厂实际运行特点,对TFT-LCD面板项目节能具有较高的指导价值。